TheDose

Pca

Also known as Pyrrolidone Carboxylic Acid, Pyroglutamic Acid, Pidolic Acid, 2-Pyrrolidone-5-Carboxylic Acid, L-PCA

CIRPubMed

Safe

CIR Expert Panel says: safe as used in cosmetics.”

The CIR Expert Panel (2019, IJT 38(S2):5S-11S) reassessed PCA (the free acid) and its salts together, confirming they are safe in cosmetics at present practices of use and concentration, provided they are not used in formulations where N-nitroso compounds can form. PCA is the second most abundant component of the skin's natural moisturizing factor (NMF), derived from filaggrin proteolysis; stratum corneum PCA levels track filaggrin genotype and serve as a validated biomarker. As a humectant, formulations containing at least 2% PCA in an appropriate vehicle improve dry skin conditions.


Major component of the skin's natural moisturizing factor (NMF); second most abundant NMF constituent at ~12% of total

Highly hygroscopic humectant derived endogenously from filaggrin proteolysis in the stratum corneum

Effective skin conditioning agent; formulations with >=2% PCA in appropriate vehicles improve dry skin

Nonirritating and nonsensitizing at cosmetic use concentrations per CIR assessment

Stratum corneum PCA levels are a validated biomarker of filaggrin gene status


Concerns
  • · Should not be incorporated into formulations where N-nitroso compound formation is possible

CIR Expert Panel
Approved
should not be used in cosmetic products in which N-nitroso compounds can be formed
[1]
CIR Expert Panel · Jul 1, 2018Live

CIR Quick Reference Table (12/2017, revised 07/2018) — PCA row: Finding=SQ, Citation=IJT 18(S2):25-34, 1999; Final report 12/2014 availab…

PCA SQ safe as used; should not be used in cosmetic products in which N-nitroso compounds can be formed IJT 18(S2):25-34, 1999; Final report 12/2014 available from CIRQRT-122017revised072018.pdf, p. 82
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[2]
Peer-reviewed (PubMed) · Sep 1, 2019

Safety Assessment of PCA (2-Pyrrolidone-5-Carboxylic Acid) and Its Salts as Used in Cosmetics

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[3]
Peer-reviewed (PubMed) · Jun 1, 1981

Pyrrolidone carboxylic acid and the skin

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[4]
Peer-reviewed (PubMed) · Nov 1, 2009

Natural moisturizing factor components in the stratum corneum as biomarkers of filaggrin genotype: evaluation of minimally invasive methods

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[5]
Peer-reviewed (PubMed) · Jan 1, 2016

Variation in the activities of late stage filaggrin processing enzymes, calpain-1 and bleomycin hydrolase, together with pyrrolidone carb…

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Sources
5
PubMed citations
4
Evidence quality
moderate
Last verified
Re-reviewed when a new CIR / SCCS opinion publishes.